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National Institute of Allergy and Infectious Disease
NIH 3D
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NIH3D

Fe36 Iron pyridylphosphonate cluster

Generated by NIH 3D workflows using data provided by
XtalGrrl
Created:
9/9/16
Submitted:
10/5/26
Published:
10/5/26
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3DPX-003694

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Public Domain
How to cite this NIH 3D entry
150
8
Version 3

Category

Small Molecules
Small Molecules
Description

An Unprecedented Fe36 Phosphonate Cage

⊥ Department of Chemistry, La Trobe Institute for Molecular Sciences, Melbourne, Australia 3086
† Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, MS15R217, Berkeley, California 94720, United States
‡ Department of Chemistry, Texas A&M University, College Station, Texas 77842, United States
§ School of Physics, Monash University, Melbourne, Australia 3800
Inorg. Chem., 2013, 52 (4), pp 1670–1672
DOI: 10.1021/ic3020145
Publication Date (Web): January 25, 2013
Copyright © 2013 American Chemical Society
 
Abstract:The reaction of 2-pyridylphosphonic acid (LH2) with iron(II) perchlorate and iron(III) nitrate afforded an interconnected, double-layered, cationic iron cage, [{Fe36L44(H2O)48}]20+ (1a), the largest interconnected, polynuclear ferric cage reported to date. Magnetic studies on 1arevealed antiferromagnetic coupling between the spins on adjacent FeIII ions.
 
CSD Refcode MIDCEJ, *.stl files were made using the program Mercury
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