Official websites use .gov
A .gov website belongs to an official government organization in the United States.

Secure .gov websites use HTTPS
A lock () or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.

National Institute of Allergy and Infectious Disease
NIH 3D
FAQsBioArt

Official websites use .gov
A .gov website belongs to an official government organization in the United States.

Secure .gov websites use HTTPS
A lock () or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.

NIH3D

Fe36 Iron pyridylphosphonate cluster

Created by
XtalGrrl
Created:
9/9/16
Submitted:
3/6/23
Published:
3/6/23
MIDCEJ_7_NIH3D.

Select an image below to view

3DPX-003694

Licensing:

Public Domain
How to cite this NIH 3D entry
26
1
Version 2

Category

Small Molecules
Small Molecules
Description

An Unprecedented Fe36 Phosphonate Cage

⊥ Department of Chemistry, La Trobe Institute for Molecular Sciences, Melbourne, Australia 3086
† Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, MS15R217, Berkeley, California 94720, United States
‡ Department of Chemistry, Texas A&M University, College Station, Texas 77842, United States
§ School of Physics, Monash University, Melbourne, Australia 3800
Inorg. Chem., 2013, 52 (4), pp 1670–1672
DOI: 10.1021/ic3020145
Publication Date (Web): January 25, 2013
Copyright © 2013 American Chemical Society
 
Abstract:The reaction of 2-pyridylphosphonic acid (LH2) with iron(II) perchlorate and iron(III) nitrate afforded an interconnected, double-layered, cationic iron cage, [{Fe36L44(H2O)48}]20+ (1a), the largest interconnected, polynuclear ferric cage reported to date. Magnetic studies on 1arevealed antiferromagnetic coupling between the spins on adjacent FeIII ions.
 
CSD Refcode MIDCEJ, *.stl files were made using the program Mercury
Source Data Details
Attribution Instructions